Quantum Mechanics

The Schrödinger Equation

The cornerstone of non-relativistic quantum mechanics — a wave equation describing how the quantum state of a system evolves over time.

Time-dependent form

$$i\hbar\,\frac{\partial}{\partial t}\Psi(\mathbf{r},t) = \hat{H}\,\Psi(\mathbf{r},t)$$

Time-independent form

$$\hat{H}\,\psi(\mathbf{r}) = E\,\psi(\mathbf{r})$$

What the symbols mean

Formulated by Erwin Schrödinger in 1926, this equation plays the same role in quantum mechanics that Newton's second law plays in classical mechanics. It is a linear partial differential equation whose solution $\Psi$ contains all physically accessible information about the system.

$i$ Imaginary unit, $i^2 = -1$
$\hbar$ Reduced Planck constant $h/(2\pi) \approx 1.055 \times 10^{-34}\,\text{J·s}$
$\Psi$ Wave function — its squared modulus $|\Psi|^2$ gives the probability density
$\hat{H}$ Hamiltonian operator — represents the total energy of the system
$E$ Energy eigenvalue of the stationary state

As a bonus, the famous mass–energy equivalence: $E = mc^2$, where $c \approx 3 \times 10^8\,\text{m/s}$ is the speed of light.